With a CYA level of 100 you want to run your chlorine higher. I've attached a chart that shows you should run min 8ppm for a CYA of 100. Your high CYA is allowing the chlorine to stay in the pool longer but is not effectively sanitizing your pool if you are around 5ppm, you will eventually get an algae bloom when you water really heats up. I learned this the hard way the first year I had my pool. I used pucks which add CYA and I was running 1ppm-3ppm of chlorine based on what I had read on the test strips and had real problems with algae that was 4 years ago since then, my CYA hovers around 100 and I have my chlorine at 10ppm and have never seen algae again.
Also with the OTO you are just checking Total Chlorine (Combined Chlorine + Free Chlorine). You really need to know your Free Chlorine.
Stabilizer . . . . . . . Min. FC . . . . Max FC . . . 'Shock' FC
=> 0 ppm ... . . . . . . 1 ppm . . . . . 3 ppm . . . . 10 ppm
=> 10 - 20 ppm . . . . 2 ppm . . . . . 5 ppm . . . . 12 ppm
=> 30 - 50 ppm . . . . 3 ppm . . . . . 6 ppm . . . . 15 ppm
=> 60 - 90 ppm . . . . 5 ppm . . . . . 10 ppm . . .. 20 ppm
=> 100 - 200 ppm . . 8 ppm . . . . . 15 ppm . . .. 25 ppm
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