If it doesn't come off, than you may have some type of metal in your pool staining your liner. Its a pretty common problem. Is your pool water municipal or from a well? Ground water tends to have more minerals in it and can stain you pool. My in-laws, bless their hearts, use a copper based sanitation system in their pool and they get similar stains along the water line. Can't convince them to switch to BBB.

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) When you see pool water that is not as reflective as usual or has a slight green or greenish-blue cast, or a surface (skimmer wier or pump basket, a shallow step or return jet) that feels a bit slippery to the touch, then the diagnosis is easy. Some type of green algae is spreading rapidly. But other forms are less obvious in their approach.