How to test bottled bleach?

[JohnT]

I've seen some 3% off-brands around, and I think I recall seeing even less - like 2.something% in Kroger.

If they won't even print the concentration, I'd be real leery of it.

Kroger carries a 2.75% bleach.

[crsuarez]

ok, CarlD's directions worked...i used 1.8ML of the HomeBest bleach in between 10 and 17 litters (I just poured water into a 17 litter bucket without filling it) of non-pool water and I got a reading of 9ppm. Without being accurate I would think that the strength of the bleach is 5.25 or above and not 3%, correct?

[KurtV]

ok, CarlD's directions worked...i used 1.8ML of the HomeBest bleach in between 10 and 17 litters (I just poured water into a 17 litter bucket without filling it) of non-pool water and I got a reading of 9ppm. Without being accurate I would think that the strength of the bleach is 5.25 or above and not 3%, correct?

Probably. If you used city water to dilute the sample, it probably had something less than 4 or so ppm free chlorine (I think 4.5 is the recommended max). My tapwater is usually about 2 ppm FC and 1 CC (chloramines are actually used for sanitation of drinking water).

[hamop78]

I test every batch of bleach I buy ---- Using 1000 ml (1 Liter) of UNCHLORINATED water (from a well or distilled), place .1 ml of the sample from your bleach bottle -- mix and test.

As for the dilution method for testing bleach I use a 1000 ml volumetric flask and a medical syringe used to perform the standard tuberculin “Tine” test. The syringe has a total capacity of 1 ml but is graduated in .01ml graduation intervals with major graduations at .1ml. The dilution method is accurate within .1 ml @20 deg C.
Testing is done using the FAS-DPD method, using a 25ml sample size, again yielding accuracy within .2 ppm in a 10000 to 1 dilution.

I have found the results to be repeatable with a 95% confidence level (in scientific terms [95 out of 100 tests]).

The results of the test is equal to the percentage of bleach.

[ChuckD]

Now there's a sticky.
Thanks, very useful!

[CarlD]

I test every batch of bleach I buy ---- Using 1000 ml (1 Liter) of UNCHLORINATED water (from a well or distilled), place .1 ml of the sample from your bleach bottle -- mix and test.

As for the dilution method for testing bleach I use a 1000 ml volumetric flask and a medical syringe used to perform the standard tuberculin “Tine” test. The syringe has a total capacity of 1 ml but is graduated in .01ml graduation intervals with major graduations at .1ml. The dilution method is accurate within .1 ml @20 deg C.
Testing is done using the FAS-DPD method, using a 25ml sample size, again yielding accuracy within .2 ppm in a 10000 to 1 dilution.

I have found the results to be repeatable with a 95% confidence level (in scientific terms [95 out of 100 tests]).

The results of the test is equal to the percentage of bleach.

Hey, anybody can do it with THOSE tools!

(just kidding! )

The reason I used the 1.8ml and 5 gallon bucket is that Ben's PS-232 kit has a measure that really close to what you need--and EVERYONE can get a 5 gallon bucket.

Another idea: Lots of infants' medicines have eyedroppers marked off in ML, some with exactly 1.0 ML. Take one from a used-up or expired bottle, and mix it with 10 liters of water. (wash it first! )

10 liters???? What's that???? Why, that's five 2-liter soda bottles! --in that good old reliable 5 gallon bucket. You probably have at least one 2-liter bottle in your recycling right now.

What you lose in precise measuring that hamop78 does will be gained by using ten times as much water and bleach, so your results should be as accurate as his. But you don't look as cool!

[cleancloths]

Not sure I understand why the need to test bleach? So what if it is not exactly 5.25% or 6%, you will know what you've got once you test your pool. I think there is more variability in the chlorine demand of the pool than there is of the bleach.

[KurtV]

cleancloths,
Bingo.

[aylad]

Not sure I understand why the need to test bleach? .

The original problem was that the concentration wasn't listed on the bottle....and there's a huge difference between 3% bleach and 6% bleach when it comes to amounts needed and lugging that many bleach jugs around!

Janet