Before worrying about that stain, you need to get your pH up ASAP. Anything lower than 7.0 is acidic and can damage your liner. And, since 6.8 is the lowest most kits can't show, your pH may actually be much lower than that. Add a box of 20 Mule Team Borax (laundry aisle at Walmart) slowly to the skimmer breaking up any clumps. Wait a couple hours, retest pH and redose until you get it above 7.0. Once it starts moving, you may want to add 1/2 box at a time.
The procedure for lowering alk can be found here:
http://www.poolsolutions.com/gd/lowe...p-by-step.html
As far as chlorine goes, yours is a little low. Chlorine levels are based on CYA levels. With a CYA of 30, your chlorine should be between 3-6 all the time. (Take a look at the Best Guess chart in my signature below.)
Now, about the stain. Do you ever bring your chlorine up to shock level which for a pool with a CYA of 30 would be about 15ppm? If not, why don't you try doing that for a few days to make sure it isn't a type of algae. Test your water 2 or 3 times per day and each time add enough bleach to get back to 15. When you can go from sundown one day until sunup the next day without losing more than 1ppm, you'll know that there is no algae in the pool and you can let the cl drift down to 3-6. Then you'll know that the stains aren't algae and we can help you try a couple other things to get rid of them. But, the first thing to rule out is algae.
By the way, welcome to the forum! Glad to have you here!
If you tell us your volume, we can help you figure out how much bleach you'll need to add.
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